There are 2 things you are referring to I believe.
You can create a cron event in the Scheduled Events section as the guide shows. I'm not at my HG setup now so I can't get exact steps but it looks reasonably good in the guide.
Secondly, to utilize any of these events, you have to use the Scheduled ON/OFF APP or write some of your own code (C#, JS, Wizard script, etc). The easiest way is to use the existing Scheduled ON/OFF APP. Go to a module and click the gear icon in the upper right corner. Select "Scheduled ON/OFF" from the drop down. Enter a valid cron expression as described in the guide I liked before. Select "control device on a given schedule" check box. Click update.
The Scheduled ON/OFF APP is simply a C# script that is provided by Gene. If you want to do something more/different, you can either write your own in any available language or modify something that already exists.